Transition-Metal Defects in Silicon

New Insights from Photoluminescence Studies of Highly Enriched 28Si

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Springer


Collection :

Springer Theses

Paru le : 2013-02-26



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Description
The fundamental properties of deep luminescence centres in Si associated with transition metals such as Cu, Ag, Au, and Pt have been a focus of interest for decades, both as markers for these deleterious contaminants, and also in the quest for efficient Si-based light emission.
 
This dissertation presents the results of ultra-high resolution photoluminescence studies of these centres in specially prepared, highly enriched 28-Si samples. The greatly improved spectral resolution due to this enrichment led to the discovery of isotopic fingerprints. These fingerprints have revealed that the detailed constituents of all of the centres previously studied had been identified incorrectly. They also revealed the existence of several different families of impurity complexes containing either four or five atoms chosen from Li, Cu, Ag, Au, and Pt. These centres’ constituents have been determined, together with no-phonon transition energies, no-phonon isotope shifts, local vibrational mode energies, and the isotope shifts of the local vibrational mode energies. The data presented here for these centres should prove useful for the currently sought theoretical explanations of their formation, stability, and properties.
Pages
97 pages
Collection
Springer Theses
Parution
2013-02-26
Marque
Springer
EAN papier
9783642350788
EAN EPUB
9783642350795

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0
Nombre pages imprimables
9
Taille du fichier
1669 Ko
Prix
94,94 €